What kind of particles do acids produce




















The larger the value of pK a , the smaller the extent of dissociation. A weak acid has a pK a value in the approximate range of -2 to 12 in water. Acids with a pK a value of less than about -2 are said to be strong acids. A strong acid is almost completely dissociated in aqueous solution; it is dissociated to the extent that the concentration of the undissociated acid becomes undetectable.

Acetic acid dissociation : The acetic acid partially and reversibly dissociates into acetate and hydrogen ions. What is the pK a for acetic acid? This reaction has a special equilibrium constant denoted K W , and it can be written as follows:. Here we have the reason that neutral water has a pH of 7. This relationship will always apply to aqueous solutions.

It is a quick and convenient way to find pH from pOH, hydrogen ion concentration from hydroxide ion concentration, and more.

The pH and pOH Scale : Relation between p[OH] and p[H] brighter red is more acidic, which is the lower numbers for the pH scale and higher numbers for the pOH scale; brighter blue is more basic, which is the higher numbers for the pH scale and lower numbers for the pOH scale. Generically, this p-notation can be used for other scales. However, because these values are often very small for weak acids and weak bases, the p-scale is used to simplify these numbers and make them more convenient to work with.

Quite often we will see the notation pK a or pK b , which refers to the negative logarithms of K a or K b , respectively. Interactive: pH : Test the pH of things like coffee, spit, and soap to determine whether each is acidic, basic, or neutral.

Visualize the relative number of hydroxide ions and hydronium ions in solution. Switch between logarithmic and linear scales. Investigate whether changing the volume or diluting with water affects the pH. Or you can design your own liquid! Privacy Policy. Skip to main content. Acids and Bases.

Search for:. Acids and Bases Nature of Acids and Bases Acids and bases will neutralize one another to form liquid water and a salt. Learning Objectives Describe the general properties of acids and bases, comparing the three ways to define them. A base is a substance that can accept protons or donate a pair of valence electrons to form a bond. Bases can be thought of as the chemical opposite of acids.

A reaction between an acid and base is called a neutralization reaction. The strength of an acid refers to its ability or tendency to lose a proton; a strong acid is one that completely dissociates in water. Key Terms valence electron : Any of the electrons in the outermost shell of an atom; capable of forming bonds with other atoms.

Lewis base : Any compound that can donate a pair of electrons and form a coordinate covalent bond. Lewis acid : Any compound that can accept a pair of electrons and form a coordinate covalent bond. The Arrhenius Definition An Arrhenius acid dissociates in water to form hydrogen ions, while an Arrhenius base dissociates in water to form hydroxide ions.

Learning Objectives Recall the Arrhenius acid definition and its limitations. The Arrhenius definitions of acidity and alkalinity are restricted to aqueous solutions and refer to the concentration of the solvent ions. The universal aqueous acid—base definition of the Arrhenius concept is described as the formation of a water molecule from a proton and hydroxide ion. Therefore, in Arrhenius acid—base reactions, the reaction between an acid and a base is a neutralization reaction.

The conjugate base is the ion or molecule remaining after the acid has lost its proton, and the conjugate acid is the species created when the base accepts the proton. Interestingly, water is amphoteric and can act as both an acid and a base. Therefore, it can can play all four roles: conjugate acid, conjugate base, acid, and base. Compounds that contain hydrogen bound to a nonmetal are called nonmetal hydrides. Metal hydrides , on the other hand, contain hydrogen bound to a metal.

Because these compounds contain hydrogen in a -1 oxidation state, they dissociate in water to give the H - or hydride ion. A similar pattern can be found in the chemistry of the oxides formed by metals and nonmetals. Nonmetal oxides dissolve in water to form acids. CO 2 dissolves in water to give carbonic acid, SO 3 gives sulfuric acid, and P 4 O 10 reacts with water to give phosphoric acid.

Metal oxides , on the other hand, are bases. Metal oxides formally contain the O 2- ion, which reacts with water to give a pair of OH - ions. We see the same pattern in the chemistry of compounds that contain the OH, or hydroxide, group. The table below summarizes the trends observed in these three categories of compounds. Metal hydrides, metal oxides, and metal hydroxides are bases. Nonmetal hydrides, nonmetal oxides, and nonmetal hydroxides are acids.

The acidic hydrogen atoms in the non-metal hydroxides in the table above aren't bound to the nitrogen, sulfur, or phosphorus atoms. In each of these compounds, the acidic hydrogen is attached to an oxygen atom. These compounds are therefore all examples of oxyacids.

Skeleton structures for eight oxyacids are given in the figure below. As a general rule, acids that contain oxygen have skeleton structures in which the acidic hydrogens are attached to oxygen atoms. Click here to check your answer to Practice Problem 1. To understand why nonmetal hydroxides are acids and metal hydroxides are bases, we have to look at the electronegativities of the atoms in these compounds. Let's start with a typical metal hydroxide: sodium hydroxide.

As a result, the electrons in the Na O bond are not shared equally these electrons are drawn toward the more electronegative oxygen atom. We get a very different pattern when we apply the same procedure to hypochlorous acid, HOCl, a typical nonmetal hydroxide.

As a result, the electrons in the Cl O bond are shared more or less equally by the two atoms. There is no abrupt change from metal to nonmetal across a row or down a column of the periodic table.

We should therefore expect to find compounds that lie between the extremes of metal and nonmetal oxides, or metal and nonmetal hydroxides.

She is a chemist at Duke University in Durham, N. Water H 2 O is chemically neutral. That means it is neither an acid nor a base. But mix an acid with water and the water molecules will act as bases. Mix water with a base and that water will play the part of the acid. Now the water molecules give up their own protons to the base and become what are known as hydroxide Hy-DROX-ide molecules. To identify acids from bases, and the relative strength of each, chemists tend to use a pH scale.

Seven is neutral. Anything with a pH below 7 is acidic. Anything with a pH above 7 is basic. One of the earliest tests to determine acids from bases was the litmus test. A chemical patch turned red for acids, blue for bases.

Today chemists can also use pH indicator paper, which turns every color of the rainbow to indicate how strong or weak an acid or base is.



0コメント

  • 1000 / 1000